Nuclear spin selective alignment of ethylene and analogues.
نویسندگان
چکیده
We investigate the alignment of ethylene and of some of its analogues via short, non-resonant laser pulses and show that it depends crucially on the nuclear spin of the molecules. We calculate the time-dependent alignment factors of the four nuclear spin isomers of ethylene and analyze them by comparison with the symmetric top molecule allene. Moreover, we explore how the nuclear spin selective alignment depends on the asymmetry of the molecules and on the intensity of the laser pulse. As an application, we discuss how nuclear spin selective alignment could be applied in order to separate different isotopomers of ethylene.
منابع مشابه
0 Theory of nuclear spin conversion in ethylene
First theoretical analysis of the nuclear spin conversion in ethylene molecules
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عنوان ژورنال:
- The Journal of chemical physics
دوره 134 20 شماره
صفحات -
تاریخ انتشار 2011